Understanding Natural Gas Composition Analysis
Natural gas composition testing is used to verify product quality, confirm compliance with specifications and generate the data needed for commercial billing. Gas chromatography separates and measures the individual components present in a natural gas sample, providing the compositional data used to calculate calorific value, Wobbe Index and related properties.
✔ Covers natural gas testing workflows used at processing facilities, LNG terminals and custody transfer points
✔ Explains standards such as ASTM D1945, ISO 6976 and GPA 2172
✔ Practical guidance on natural gas GC system configuration
Hydrocarbons and permanent gases measured by GC
Natural gas contains methane, higher hydrocarbons and permanent gases including nitrogen, carbon dioxide and oxygen. Each component influences energy content and commercial value.
Gas chromatography separates and measures each component individually, providing a detailed view of the gas composition.
Standards used in natural gas analysis
Several standards define how natural gas composition is measured and how the results are used to calculate calorific value, Wobbe Index and other properties.
These include ASTM D1945, ISO 6974, ISO 6976, ASTM D3588 and GPA 2172.
Understand how a natural gas GC system is configured
Natural gas analysis requires a purpose-configured GC system capable of measuring both permanent gases and hydrocarbons in a single run.
This includes dual-detector configuration, column selection and sample handling considerations.
Why Natural Gas Composition Analysis Matters
Natural gas is bought and sold based on energy content. The calorific value of a gas stream is determined by its composition, and that composition can vary significantly depending on the source.
Where Natural Gas Composition Analysis Is Required
Natural gas composition testing takes place at several points in the supply chain.
This typically includes gas processing facilities, LNG import terminals, custody transfer points, storage facilities and quality control laboratories.
Standards Used in Natural Gas Testing
Several recognised standards define how natural gas composition is measured, reported and used to calculate physical properties.
These include ASTM D1945 and ISO 6974 for composition analysis, and ISO 6976, ASTM D3588 and GPA 2172 for property calculations.
Components Measured in Natural Gas by GC
The composition of a natural gas stream determines its calorific value, its suitability for different applications and whether it meets the required specification.
Components typically measured include methane, higher hydrocarbons and inert gases such as nitrogen, carbon dioxide and oxygen, each with a distinct role in defining gas quality and energy content.
Calculated Properties from Composition Data
Composition data from gas chromatography is used to calculate the physical and commercial properties of natural gas.
These include calorific value, Wobbe Index, specific gravity, density and compressibility factor.
Selecting a GC System for Natural Gas Analysis
Natural gas analysis requires a purpose-configured GC system capable of measuring both permanent gases and hydrocarbons across a wide concentration range in a single run.
Detector selection, column configuration, sample handling and hydrocarbon range all influence how the system is specified for this application.
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Who Uses Natural Gas Composition Analysis?
Natural gas composition analysis by gas chromatography is carried out in a range of laboratory settings across the gas supply chain.
Raw natural gas extracted from the ground must be characterised before it can be processed or sold.
Composition analysis at processing facilities confirms the hydrocarbon content of incoming feed gas and monitors the output of processing operations to verify that treated gas meets downstream quality requirements.
When liquefied natural gas arrives by ship and is regasified for distribution, composition analysis confirms the gas meets the specification required for grid injection.
Testing at this stage verifies calorific value, Wobbe Index and individual component concentrations before the gas enters the distribution network.
When natural gas changes hands between a producer, transporter or buyer, composition must be measured accurately to determine its commercial value.
The resulting data is used to calculate calorific value and related properties that form the basis for billing and contractual settlement.
Laboratories involved in gas analysis, third-party testing or regulatory compliance carry out natural gas composition testing as part of routine quality control work.
Gas chromatography provides a repeatable, accurate method for measuring composition and reporting results in compliance with recognised industry standards.
If you are evaluating natural gas analysis methods, we can review your requirements.
Download to Learn More
Understanding natural gas composition analysis requires clear information on both the analytical method and the GC system configuration.
The Natural Gas Composition Analysis Buyers Guide brings this information together in a single technical resource covering testing workflows, standards, components, calculated properties and GC system configuration.
Download the guide to see:
• how natural gas composition is measured using gas chromatography• where natural gas testing takes place across the supply chain
• the components typically measured during natural gas analysis
• the properties calculated from composition data, including calorific value and Wobbe Index
• factors involved in configuring a GC system for natural gas analysis
Download the Buyers Guide
Frequently Asked Questions
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What components are typically measured in natural gas analysis?
Natural gas analysis by gas chromatography typically measures methane, ethane, propane, isobutane, n-butane, pentanes, carbon dioxide, nitrogen and oxygen.
Each component plays a distinct role in defining the overall gas composition and influences the calculated properties used for commercial and quality purposes.
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Why are two detectors used in natural gas analysis?
Natural gas contains both hydrocarbon components and permanent gases such as nitrogen, oxygen and carbon dioxide. Flame ionisation detectors respond to hydrocarbons but not to permanent gases. Thermal conductivity detectors provide a universal response that covers both.
Running both detectors in parallel allows the full composition to be measured in a single analysis run.
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What properties can be calculated from GC composition data?
From the measured composition, properties including calorific value (superior and inferior), Wobbe Index, specific gravity, real density and compressibility factor can be calculated.
Calculation methods are defined in standards including ISO 6976, ASTM D3588 and GPA 2172.
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How is natural gas introduced to the gas chromatograph?
Natural gas is introduced as a gas phase sample using a gas sampling valve. A fixed volume is taken at or close to line pressure and injected into the GC system.
Unlike LPG, natural gas does not require a liquid sampling approach.
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What is the difference between standard and extended hydrocarbon analysis?
In standard natural gas analysis, hydrocarbons from C6 upwards are reported as a single grouped value. This is sufficient for most pipeline gas applications where heavier components are present in very low concentrations.
Extended analysis separates individual components from C6 through to C12, and is used where more detailed characterisation of the heavier hydrocarbon fraction is required.
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Where is natural gas GC analysis commonly carried out?
Natural gas GC analysis is commonly performed at gas processing plants, LNG import and regasification terminals, custody transfer metering points and quality control laboratories.
Testing at these locations confirms gas composition, supports commercial billing and verifies compliance with specifications and grid injection requirements.